OSCAR · Operando study of the catalytic activity of gold nanoparticles by Surface Differential Reflectivity Spectroscopy (SDRS): from plasmonic response to morphology
Horizon 2020 — Marie Skłodowska-Curie Actions
- Duration
- 2016-03-31 → 2018-03-30
- EU contribution
- €173,076
- Participants
- 1
- Scheme
- MSCA-IF-EF-ST
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Results in brief
Operando study of the catalytic activity of gold nanoparticles by Surface Differential Reflectivity Spectroscopy (SDRS): from plasmonic response to morphology
The outstanding catalytic activity of gold nanoparticles (NPs) on metal-oxide supports has attracted enormous attention not only on a fundamental point of view but also for technological applications related to the demand of a new generation of more efficient and more selective catalysts. The puzzling fact is that extended faces of gold are inert while particles below a few nanometers in size become active. Following the early finding of an increase of the activity per gold atom when the NP size decreases, numerous studies have been devoted to the determination of the relationship between NP morphology, support nature and their catalytic activity. The OSCAR project has coped this issue by combining a battery of surface science techniques for exploring the model systems of Au/TiO2(110).
Data: CORDIS, © European Union
Project objective
The outstanding catalytic activity of gold nanoparticles (NPs) on metal-oxide supports has attracted enormous interest not only for fundamental understanding but also for the design and synthesis of a new generation of efficient catalysts. At the current time, one of the main technical challenges for gold catalyst applications is the stability in terms of sintering during use. As for many heterogeneous catalysts, the characterization of the gold NPs morphology in operating conditions is essential for progress towards practical use. The issue is currently treated by X-ray diffraction at synchrotron radiation facilities. The present project (OSCAR) foresees a breakthrough. It aims to develop an optical method, namely Surface Differential Reflectivity Spectroscopy (SDRS), to determine operando at the laboratory the shape and size of NPs on the basis of their plasmonic response. The challenge is to combine non-invasive SDRS measurements for determining NP morphology to reactivity measurements in realistic conditions. The case study is the archetypal case of CO oxidation on supported gold NPs, for which the relationship between NPs size/shape and reactivity is vividly debated. The catalytic activity of gold NPs will be examined both on a reducible substrate, rutile TiO2(110), and on an irreducible substrate, MgO(100) films on Ag(100), to determine the crucial role played by the supporting metal-oxide substrate.
Original text from CORDIS.
Participants
- SORBONNE UNIVERSITE · ParisCoordinatorFrance
Links
Data: CORDIS, © European Union