H2020Individual fellowship2020–2023

CoSolCat · Surfactant-free Colloidal Solutions for nano-Catalysts with enhanced properties

Horizon 2020 — Marie Skłodowska-Curie Actions

Duration
2020-05-01 → 2023-04-30
EU contribution
€268,922
Participants
2
Scheme
MSCA-IF

Lines connect the coordinator with its partners.

Results in brief

Surfactant-free Colloidal Solutions for nano-Catalysts with enhanced properties

For various applications likes chemical synthesis, energy conversion, water/air purification or medicine, precious metal are important elements. However, precious metals are non-renewable resources and in limited supply. To make the most of every single atom of the precious metal (e.g. Pt, Ir, Pd, Au, Ag, Ru, Rh, Os), designing materials down to the atomic scale is a promising and rewarding approach. Unfortunately, designing such nanomaterials is not a trivial task. In particular, in wet chemical syntheses used worldwide, many chemicals are needed to form and stabilize nanomaterials from molecular complexes. These chemicals often derived from fossil fuels and/or are toxic. For instance, surfactants are added molecules in order to stabilize the nanomaterials and control size, shape or composition. In most cases, these surfactants typically need to be removed in order to make the surface atom fully available for applications, e.g. for optimized catalysis. This removal step add complexity, cost, are often energy intensive and typically performed with moderate success. Alternatives must be proposed. Developing surfactant-free syntheses is challenging but extremely rewarding. It makes the synthesis process much simpler, safer and better controlled, for instance by being more reproducible by reducing the risk of being subject to the strong effects of impurities when using several chemicals. This simplicity can facilitate the transfer of knowledge on the synthesis to larger scale. It leads to catalysts with higher activity, which is highly desired to make the most of the precious metal resources. Overall, this makes surfactant-free syntheses very promising platforms to develop for both fundamental, applied and industrial research and development. The overall objective of the CoSolCat project (Surfactant-free Colloidal Solutions for nano-Catalysts with enhanced properties) is to explore the full benefits of new surfactant-free syntheses. Despite the Covid-19 pandemic and the related limitations, 15 peer-reviewed publications were published in relation to the project and one patent application placed in summer 2021, with ongoing discussions with an industrial partner to test/benchmark the technology. I also secured a Tenure Track Assistant Professor position which is a significant step further in an academic career. Information can be found on the general webpage: https://chem.ku.dk/ansatte/alle/?pure=en/persons/509101, since no specific website has been developed for the project. A link to the projects on CORDIS is also made on my new research group website: http://nestresearchlab.com/The%20Team/

Data: CORDIS, © European Union

Project objective

CoSolCat is based on a new surfactant-free colloidal synthesis of precious metal nanoparticles developed and patented by the experienced researcher Dr J. Quinson. The technology has attracted interest from industries and a start-up has been created, yet is in its very early stages. Further research is required to fully seize and position the technology as a new state–of –the –art method to produce precious metal nanocatalysts. The objectives of CoSolCat are to study in detail and develop further surfactant-free syntheses of precious metal-based nanoparticles to be used as catalysts with enhanced performances for the production of valuable chemicals and energy applications. By combining world-leading expertise from the University of Copenhagen (Assistant-Professor Maria Escudero Escribano), Stanford (Assistant Professor Matteo Cargnello), a start-up and his own experience, Dr J. Quinson will produce, study, characterise, compare and so benchmark nanocatalysts obtained by the technology he patented, new routes to-be-developed in the project, and state-of-the art methods.This will provide a deeper understanding of the production and properties of precious metal catalysts while the new technology will be more controlled and optimised to a degree relevant for industry. E.g. bi-metallic nanoparticles comprising a non-precious metal will be developed for the first time with new surfactant-free approaches and studied for model hydrogenation reactions. This research will lead to sustainable and affordable catalysts with improved selectivity.The expertise gained by the applicant will (1) help to mature the technology, (2) develop a new pool of competences in heterogeneous catalysis in Europe, (3) provide expertise in industrially relevant production of catalysts suitable for a range of chemical productions and energy conversion reactions. The proposal is then directly relevant to provide world leading expertise in Europe for a green and more sustainable economy.

Original text from CORDIS.

Participants

  • KOBENHAVNS UNIVERSITET · KOBENHAVNCoordinatorDenmark
  • BOARD OF TRUSTEES OF THE LELAND STANFORD JUNIOR UNIVERSITY · STANFORDUnited States

Links

Data: CORDIS, © European Union