H2020Individual fellowship2021–2023

PPMTFD · Programmable polymer microarrays for tunable and flexible display

Horizon 2020 — Marie Skłodowska-Curie Actions

Duration
2021-02-15 → 2023-03-28
EU contribution
€224,934
Participants
1
Scheme
MSCA-IF

Lines connect the coordinator with its partners.

Results in brief

Programmable polymer microarrays for tunable and flexible display

This Marie Skłodowska Curie Action (MSCA) titled “Programmable Polymer Microarray for Tunable and Flexible Display” aimed to develop a new kind of information storage and display and anti-counterfeiting technology with colorful switch state and low power consumption, this display doesn’t have the backlight module like liquid crystal displays (LCD) and self-illumination light like organic light-emitting diode displays (OLEDs), it can protect our eyes and provide a more comfortable and convenient reading experience. What’s more, the security of the displayed information has been greatly improved. The future is a world of screens. Not only televisions, computers, mobile phones and open air large screens, but also the surface of tables or walls, as well as the displays inside vehicles showing real-time information. LCD and OLED are now conventional display technologies that have been extensively used in smart phones, televisions, tablets and many other displays. However, they also have problems such as high energy consumption, visual impairment after long-term reading and large volume. In order to meet the increasing demand of portable and electronic products and low energy consumption, new display technologies are highly desired. At the same time, counterfeiting threatens the information security of individuals and society, so it is also necessary to improve information security while displaying information. The MSCA Fellow has focused on four major objectives: 1) synthesize new kind of stimuli-responsive molecules for the novel information display and anti-counterfeiting; 2) study the kinetics of energy transfer between stimuli-responsive molecules and fluorophores for dynamic emission; 3) fabricate the functional molecules doped polymer microarray for the preparation of display panel; 4) modulate the molecules ratios and external stimulations to obtain the colorful and flexible display. In addressing these objectives, this project will report on the development of a kind of stimuli-responsive compound-indole dimer which displayed multiple stimuli-driven chromotropic capabilities, when triggered by stimuli, the color of the compound changes rapidly, accompanied by reversible changes in fluorescence. Interestingly, the color changes of the indole dimer were orthogonal to those of the traditionally utilized stimuli-responsive spiropyran (SP). In combination, this allowed the preparation of invisible inks for printing, with security of information encrypted based on their diametrically opposed response to thermal and acid/base stimulation. The MSCA Fellow will also show the kinetics of the photo-isomerization of spiropyran, the FRET process of the composite, a programmable FRET process is developed to obtain tunable outputs. More importantly, flexible microarrays are fabricated from such fluorochromic mixtures by inkjet printing. The dynamic FRET process can also be constructed and generate tunable fluorescence in the ready-made microstructures. These created flexible patterns based on the functional microarrays can be used as novel optically readable media for information storage and display.

Data: CORDIS, © European Union

Project objective

The future is a world of screens. Not only TVs, computers, phones and open air screens, but also the surface of tables or walls, as well as the displays inside vehicles showing real-time information. Liquid crystal displays and organic light-emitting diode displays are now conventional displays that have been extensively used in smart phones, TVs, tablets and many other displays. However, their intrinsic limitations such as monotonous color, power needs and minimal deformations, significantly restrict future developments. In order to meet the increasing demand of portable electronic products and wearable devices, new display technologies including microscale and flexible displays with tunable properties are highly desired. In this proposal, I will design novel types of tunable and flexible displays based on programmable polymer microarrays (PPM). The core technology is that the displays response speed will be greatly enhanced by designing the structure of functional photochromic molecules. Photochromic spiropyrans (SP) and the fluorescent dye (perylene bisimide, PBI) will be introduced into PPM and used as energy acceptors and donors, respectively. The display process can be tunable through reversibly fluorescence resonance energy transfer between SP and PBI upon different light irradiation. This means that vivid color image displays will be able to be written, erased, and rewritten repeatedly. The new displays will possess advanced response speeds with new SP generated with a range of push-pull substituents. Importantly, the flexible polymeric matrix will expand the scope of display applications because of its stretchable, bending and crimp deformation ability. Moreover, the microscale feature of current designs will be beneficial for integrating displays onto the chip to meet the requirements of miniaturization of devices. The generated programmable and flexible optical microstructures would contribute to the next-generation platforms of smart displays.

Original text from CORDIS.

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Data: CORDIS, © European Union