HAEMOGLOBIN · From biomass to catalysts and chemicals: exploiting blood and food waste towards high-value products.
Horizon 2020 — Marie Skłodowska-Curie Actions
- Duration
- 2020-06-10 → 2022-06-09
- EU contribution
- €212,934
- Participants
- 1
- Scheme
- MSCA-IF
Lines connect the coordinator with its partners.
Results in brief
From biomass to catalysts and chemicals: exploiting blood and food waste towards high-value products.
Catalysts are entities that are able to accelerate chemical reactions. This is crucial for our society, since they can drastically reduce the reaction time (from years to hours in the most extreme cases) to prepare useful chemicals, while also lowering energy consumption of a given process. Their contribution to society amounts to almost 40% of world's GDP since they are needed in most chemical processes, ranging from drug manufacturing to agricultural applications, or plastics for instance. However most catalysts are based on precious and expensive metals, such as Palladium or Platinum. For the countries of the EU, these metals have to be imported from foreign countries, with questionable labour laws and with ever-increasing and volatile prices. Furthermore, most metals are toxic and need to be treated carefully if they are involved in the making of products destined to be consumed by human beings, such as drugs. Alternatives mustbe found to reduce our reliance on precious metals. One solution consists in extracting metals from industrial waste. For instance, slaughterhouses produce considerable amounts of blood waste, that cannot be easily disposed of, and could be reused. In particular, the oxygen-carrying protein contained in blood, hemoglobin, naturally contains iron atoms. While these atoms are normally involved in the transportation of oxygen, it could be used for other catalytic applications. Our goal here is to make an iron-based catalyst from hemoglobin, and apply it to industrially-relevant catalytic applications.
Data: CORDIS, © European Union
Project objective
The aim of this proposal is to make universal and low-cost catalysts from industrial waste and apply them to biomass upgrading. To that end, we will make single atomic FeNx sites supported on carbon (FeNx@C) that have seen tremendous development in organic chemistry in the past 5 years. Indeed, they are active for both oxidations and reductions, and constitute promising substitutes for toxic, scarce and costly platinum-group metals (PGM). Yet major challenges remain in the field: first we need to find new routes to drastically lower the footprint of their synthesis. Here we will adopt a bio-inspired approach and use inexpensive hemoproteins as precursors: they naturally contain four pre-built FeNx sites (hemes) per unit. Hemoproteins can be extracted from blood in slaughterhouse waste. We will use the resulting catalysts for the upgrading of key biomass-derived platform molecules: 5-hydroxymethylfurfural (5-HMF), levulinic acid (LA), and other biomass-derived alcohols.The reductive and oxidative potency of FeNx@C will be first explored separately, then sequentially for alcohol direct conversion to amines. Due to their heterogeneous nature, FeNx@C catalysts can be readily transposed to continuous flow synthesis. With such promising technology, we will fully exploit biomass to both make new catalysts and perform large scale conversion of bio-based platform chemicals.
Original text from CORDIS.
Participants
- IMPERIAL COLLEGE OF SCIENCE TECHNOLOGY AND MEDICINE · LondonCoordinatorUnited Kingdom
Links
Data: CORDIS, © European Union
