ENTERPRISE · vEnturing oN heTERodoped Polycyclic aRomatIc hydrocarbonS to develop smart labEls
Horizon 2020 — Marie Skłodowska-Curie Actions
- Duration
- 2021-07-01 → 2023-06-30
- EU contribution
- €174,167
- Participants
- 1
- Scheme
- MSCA-IF
Lines connect the coordinator with its partners.
Results in brief
vEnturing oN heTERodoped Polycyclic aRomatIc hydrocarbonS to develop smart labEls
The incorporation of heteroatoms into polycyclic aromatic hydrocarbons (PAHs) is a promising and appealing approach to create hybrid graphenoid structures. These structures, when composed solely of C(sp2) atoms, may present challenges in synthesis using conventional in-solution methods and can be susceptible to chemical instability under ambient conditions. The preparation and study of extended acenes face significant limitations due to their inherent instability and low solubility. However, to overcome these challenges and unlock new possibilities, various synthetic methods and stabilisation strategies have been developed, enabling access to extended PAHs with diverse topologies. In the context of the MSCA action, the experienced researcher (Dr. Beatrice Berionni Berna) joined Prof. Davide Bonifazi's research lab at the University of Vienna, Austria. The primary focus of her work involved incorporating oxygen atoms directly into the acene backbone, starting from different building blocks (peri-xanthenoxanthene, methoxynaphthalene, and tetraarylporphyrins), resulted in pyrano-fused structures with distinct molecular geometries, electronic structures, and material properties, towards the application of the new improved structures in organic electronics, and sensing applications. The co-planarisation of the oxygen lone pair of the fused pyrano moiety with the p electronic system of the PAHs has been proven to enable a more efficient -extension, producing an electron rich set of O-fused structures with an increasing electron donating character compared to the all-carbon congener. During the action, the experienced researcher had received computational training using Vienna Scientific Cluster (VSC).
Data: CORDIS, © European Union
Project objective
The scientific goal of ENTERPRISE is to develop and apply multifunctional chromogenic heteroatom-doped polycyclic aromatic hydrocarbons to produce materials that can empower current packaging technology and elevate electrochromic displays to the age of interactivity.These smart labels can thus provide information to people in an unequivocal and yet appealing way. We plan to produce materials that, through a selective reaction with O2, irreversibly retain an oxidising event and successively communicate it as an irreversible colour change under a human input. To achieve it, we envisage to prepare hybrid O-doped chromogenic polycyclic aromatic hydrocarbons that, in the presence of O2 and light, will act as a photosensitiser producing singlet O2. The reactive O2 will interact with the chromogenic material itself to give endoperoxide species that, under an external stimulus, yield radical species initiating an irreversible coloured polymerisation. Integration of this material into a prototype electrochromic display will result in a label that operates irreversibly after it has been exposed to O2 and reversibly when not exposed to O2. Considering that the leading cause of food-spoilage is related to aerobic oxidations, we expect our results to initiate a series of further technological advancements in the field of labels for smart packaging of food, opening the door to the first O2-sensitive, user-friendly, rapid, flexible and printable label. Through this fellowship, the applicant will enhance her creative and innovative research potential and her multidisciplinary competence of organic materials, with the final goal to become a prime researcher at the interface between fundamental and applied research. This will be made possible by the coordinated effort of a focused and highly motivated young supervising team composed of a leading academic institution and a vibrant enterprise.
Original text from CORDIS.
Participants
- UNIVERSITAT WIEN · WienCoordinatorAustria
Links
Data: CORDIS, © European Union