H2020Individual fellowship2021–2024

PLECTRA · Plasmon Coupled Luminescent Solar Concentrators and their Application in Self-Supplied Electrochromic Windows

Horizon 2020 — Marie Skłodowska-Curie Actions

Duration
2021-09-01 → 2024-01-03
EU contribution
€212,934
Participants
1
Scheme
MSCA-IF

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Results in brief

Plasmon Coupled Luminescent Solar Concentrators and their Application in Self-Supplied Electrochromic Windows

Luminescent solar concentrators (LSCs) present an innovative approach to constructing integrated photovoltaic systems, capable of capturing both direct and indirect sunlight through photoluminescence and channeling it into high-efficiency solar cells. The primary challenge hindering their commercial adoption is their low efficiency, attributed to the limited light absorption by the LSC's active materials and the inadequate harnessing of the solar spectrum's full range. Our work explores the enhancement of light absorption within LSCs by incorporating particles that scatter light, varying in size and shape. This method not only increase the optical pathlength within the concentrators, leading to better absorption but also broadens the spectrum of light directed towards the solar cells, thereby elevating their efficiency. Furthermore, we have examined how these concentrators scatter light at various angles and the consequent effects on the system's overall power conversion efficiency. The implications of our research are twofold, offering both foundational insights and practical applications. The particle scattering behavior we've analyzed can improve the performance of LSCs and has potential applications in other fields, such as in the development of sunscreens and solar cells. This study is vital for advancing our utilization of renewable energy sources like solar light, emphasizing the importance of maximizing solar energy capture. The LSC technology and scattering particles we've focused on are non-toxicity, cost-effectiveness, and versatility in color. Moreover, their application extends beyond buildings to greenhouses, where they can generate electricity and modify the light spectrum to enhance plant growth. Our research aims to deepen the understanding of how light interaction with scattering particles can boost both the optical absorption of the LSCs, and, power conversion efficiencies of solar cells. This knowledge could guide the selection of particle sizes and shapes that optimize LSC applications, contributing to the broader goal of improving renewable energy technologies.

Data: CORDIS, © European Union

Project objective

Luminescent solar concentrators (LSCs) have the potential to facilitate widespread deployment of building-integrated photovoltaics (BIPV) into our cities. However, prototype devices still fail to achieve the theoretical efficiencies due to contributions from optical loss mechanisms, including light scattering. The aim of PLECTRA is to understand, control and harness the contribution of light scattering mechanisms to design efficient LSCs that can be used in BIPV. The phenomenon of plasmon-enhanced photoluminescence, in which elastic scattering from plasmonic nanoparticles boosts the photoluminescence efficiency of a luminescent species (e.g. quantum dots), will be exploited to harness scattering and improve the LSC performance. To achieve this we will use a layer-by-layer deposition approach to prepare resonator-emitter core-satellite structures, in which the two species are separated by a quantifiable distance. Single particle scattering and photoluminescence studies, will be used to determine the required separation to obtain plasmon-coupled photoluminescence (rather than quenching). Optimised species will be incorporated into LSCs and sophisticated angle-resolved scattering measurements, in conjugation with numerical simulations, will be used to evaluate the scattering pathways in the device. Finally proof-of-concept integration of the LSCs with PV cells, and subsequently electrochromic glass will be demonstrated as evidence for potential application in BIPV.

Original text from CORDIS.

Participants

  • THE CHANCELLOR MASTERS AND SCHOLARS OF THE UNIVERSITY OF CAMBRIDGE · CAMBRIDGECoordinatorUnited Kingdom

Links

Data: CORDIS, © European Union