BIOCATMAG · CATALYSIS IN AQUEOUS SOLUTION BY MAGNETIC INDUCTION: BIOMASS VALORIZATION
Horizon Europe — Marie Skłodowska-Curie Actions
- Duration
- 2023-06-01 → 2025-05-31
- EU contribution
- €195,915
- Participants
- 2
- Scheme
- HORIZON-TMA-MSCA-PF-EF
Lines connect the coordinator with its partners.
Results in brief
CATALYSIS IN AQUEOUS SOLUTION BY MAGNETIC INDUCTION: BIOMASS VALORIZATION
The transition to a greener economy requires innovative methods for producing chemicals using sustainable resources and cleaner technologies. One promising solution lies in transforming non-edible biomass, such as agricultural residues, industrial by-products, and urban waste, into valuable chemicals, including solvents, plastics, and ingredients for food and medicine. At the same time, as renewable energy sources like wind and solar become more prevalent, there is a growing need for chemical processes that can be integrated into the intermittent energy supply characteristic of these new energy sources. BIOCATMAG brings these two challenges together. The project explores the valorisation of biomass using a cutting-edge method called magnetically induced catalysis, where specifically designed magnetic catalysts heat up very fast, efficiently and generate highly localised hot spots when exposed to an alternating magnetic field (AMF). In this way, the technology has the potential to enable chemical reactions to happen exactly where and when needed, without heating the entire reactor. This not only saves energy and adapts to fluctuating energy sources, but also enables more selective and, consequently, more sustainable chemical transformations. Despite its promise, magnetically induced catalysis remains in its infancy, particularly in aqueous-phase systems. Therefore, BIOCATMAG focuses on three main objectives that target key chemical transformations in water and mild conditions. First, upgrading a cellulose-derived molecule (levoglucosenone) into greener alternatives to solvents and plastics; creating food- and pharma-relevant molecules directly from sugar and ammonia; and converting raw cellulose into high-value furan molecules using a single water-based process. In the last case, the project attempts to take advantage of the highly localized heating produced at the surface of magnetic nanoparticles to drive one reaction, while a second reaction occurs simultaneously in the cooler bulk liquid using a separate, non-magnetic catalyst, thereby allowing two distinct chemical steps to take place at two different temperatures, within the same reactor. By combining smart catalyst design with magnetic heating, BIOCATMAG aims to demonstrate that chemical production can be cleaner, more energy-efficient, and better aligned with a future powered by renewable energy. The project's results offer hope for continuing to explore new technologies in green chemistry, reducing reliance on fossil fuels, and supporting Europe’s broader goals for climate action and sustainable innovation.
Data: CORDIS, © European Union
Project objective
Within a worldwide upsurge of renewable energies and the need to replace chemicals from fossil sources, BIOCATMAG intends to offer a new catalytic approach for producing chemicals from biomass. Based on magnetically induced catalysis, where a catalyst with a magnetic response combines heating and catalytic functions under an alternate magnetic field, the technology presented would enable the coupling of intermittent renewable energies with biomass valorization. Remarkably, several challenges, but also opportunities, lie on the horizon owing to the use of magnetocatalysis. Some of them would be tuning the selectivity by changing the magnetic field amplitude, stabilizing magnetic metal nanoparticles in water or the need to accomplish cascade-type processes. Therefore, the project aims to broaden current knowledge of magnetically induced catalysis while providing a set of chemicals using unprecedented non-noble metal catalysts and greener reaction conditions, such as aqueous media and low pressures. Furthermore, the reactions have been carefully chosen to cover the main areas of interest in biomass valorization by heterogeneous catalysis. In that sense, the transformation of a next-generation platform molecule (levoglucosenone), the production of organonitrogen chemicals (pyrazines), and the valorization of cellulose will be the processes selected. This selection also considers the need to meet the challenges mentioned earlier. In that line, all reactions will be performed in aqueous media, the levoglucosenone hydrogenation or hydrogenolysis will be adjusted with the field amplitude, and, for the valorization of cellulose, a two-step one-pot process to 2,5-bis-hydroxymethylfurane is proposed. In this last case, a multicatalytic batch reactor working with two different temperature regions is proposed for the first time, taking advantage of the differential heating experimented by different metallic materials under the same alternate magnetic field exposure.
Original text from CORDIS.
Participants
Links
- View on CORDIS
- DOI: 10.3030/101109254
- https://ec.europa.eu/research/participants/documents/downloadPublic?documentIds=080166e50518469f&appId=PPGMS
- https://ec.europa.eu/research/participants/documents/downloadPublic?documentIds=080166e5200a930d&appId=PPGMS
Data: CORDIS, © European Union
