HEИндивидуална стипендия2022–2024

IONMIGRATIONPSC · Study of Ion Migration in Perovskite Solar Cells via X-ray Photoemission Spectroscopy Imaging and Photoluminescence Microscopy

„Хоризонт Европа“ — Действия „Мария Склодовска-Кюри“

Период: 2022-11-01 → 2024-10-31
Финансиране от ЕС: 185 441 €
Участници: 1
Схема: HORIZON-TMA-MSCA-PF-EF

Линиите свързват координатора с партньорите.

Накратко на български

Перовскитните слънчеви клетки се анализират, за да се проследи как се движат йонните дефекти в тях при работа. Разбирането на този процес помага за подобряване на дългосрочната стабилност на устройствата, което е важно за тяхното бъдещо индустриално приложение.

Този кратък обзор е генериран от изкуствен интелект

Кратко обяснение, генерирано от езиков модел по текста на CORDIS. Оригиналът е по-долу.

Резултати накратко

Study of Ion Migration in Perovskite Solar Cells via X-ray Photoemission Spectroscopy Imaging and Photoluminescence Microscopy

Overview: Organic-inorganic hybrid perovskite solar cells (PSCs) attract enormous attention in the field of emerging photovoltaics due to their unique opto-electronic properties and unprecedented advances in performance. In just over a decade, the power conversion efficiency (PCE) of PSCs has increased to more than 26%, suggesting this technology might be ready for large-scale exploitation in industrial applications. However, stability, scalability and toxicity are some of the major concerns that impede the commercialization of PSCs. Among these, exploring strategies to enhance the long-term stability of PSCs is a main research topic in the perovskite community. While it is generally considered that ionic defect states in the perovskite layer such as vacancies, interstitial sites, anti-site substitutions as well as surface and grain boundary defects inevitably lead to the degradation of PSCs, much remains unknown about the fundamental nature of ionic defects and in particular their migration in perovskite materials. The IONMIGRATIONPSC project aims to provide fundamental understanding of ion migration in perovskite solar cells (PSCs) and valuable insights for the enhanced device stability by a unique combination of electrical and spectroscopic methods. This project focus on tracking the changes in both compositional and optoelectronic properties of perovskite materials and correlate with the operational stability of the devices. Objectives: Quantification of ion migration in PSCs. Tracking changes in both the compositional and optoelectronic properties of perovskites as a function of applied bias in perovskite devices, with and without illumination. Correlation between the spatially resolved optoelectronic measurements and the study of perovskite degradation. Exploring the effects of passivation techniques on the ion migration. Elucidation of the role of ion migration in PSCs degradation.

Текст от CORDIS, на английски · Данни: CORDIS, © Европейски съюз

Цел на проекта

Organic-inorganic hybrid perovskite solar cells (PSCs) attract enormous attention in the field of emerging photovoltaics due to their unique optoelectronic properties and unprecedented advances in performance. In just over a decade, the power conversion efficiency of PSCs has increased from 3.9% to 25.5%, suggesting this technology might be ready for large-scale exploitation in industrial applications. However, stability and scalability are some of the major concerns that impede the commercialisation of PSCs. Among these, exploring strategies to enhance the long-term stability of PSCs is a main research topic in the perovskite community. While it is generally considered that ionic defect states in the perovskite layer such as vacancies, interstitial sites, anti-site substitutions as well as surface and grain boundary defects inevitably lead to the degradation of PSCs, much remains unknown about the fundamental nature of ionic defects and in particular their migration in perovskite materials. This project will focus on the study of ion migration by a unique combination of electrical and spectroscopic methods which will allow tracking changes in both the compositional and optoelectronic properties of perovskites with the same spatial resolution and thus directly linking the migration of ionic species to their effect on material properties. By applying this novel methodology, I will explore the effects of perovskite composition, film microstructure and mitigation strategies on the ion migration and investigate how ion migration impacts the stability of perovskite materials. This project will significantly expand our current understanding of ion migration in PSCs and provide valuable insights for enhancing device stability.

Оригинален текст от CORDIS (на английски).

Участници

TECHNISCHE UNIVERSITAET DRESDEN · DresdenКоординаторГермания